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JEE Main 2016 (9 Apr, Shift 1) · Transitions, Photon Emission & Excitation

Transitions, Photon Emission & Excitation question from JEE Main 2016 (9 Apr, Shift 1)

Q61JEE Main 2016 · 9 APR · SHIFT 1Difficult

Transitions, Photon Emission & Excitation

A hydrogen atom makes a transition from n = 2 to n = 1 and emits a photon. This photon strikes a doubly ionized lithium atom (z = 3) in excited state and completely removes the orbiting electron. The least quantum number for the excited state of the ion for the process is:

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Answer: (c)

  1. Photon energy (H, 2→12 \to 1) =10.2 eV= 10.2\text{ eV}.
  2. Ionisation energy of Li2+^{2+} from level nn: 13.6×9n2=122.4n2\frac{13.6 \times 9}{n^2} = \frac{122.4}{n^2} eV.
  3. Need 122.4n2≤10.2⇒n2≥12⇒n≥3.46\frac{122.4}{n^2} \le 10.2 \Rightarrow n^2 \ge 12 \Rightarrow n \ge 3.46.
  4. Least integer n=4n = 4 (needs 7.657.65 eV).
  5. So the answer is (c) 4.
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