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JEE Main 2013 (23 Apr, Shift 1) · Gas Laws & Ideal Gas Equation

Gas Laws & Ideal Gas Equation question from JEE Main 2013 (23 Apr, Shift 1)

Q78JEE Main 2013 · 23 APR · SHIFT 1Difficult

Gas Laws & Ideal Gas Equation

A thin tube sealed at both ends is 100 cm long. It lies horizontally, the middle 20 cm containing mercury and two equal ends containing air at standard atmospheric pressure. If the tube is now turned to a vertical position, by what amount will the mercury be displaced?

(Given: cross-section of the tube can be assumed to be uniform)

Figure

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Answer: (b)

Hg40 + x40 − x20 cmP_upP_low
  1. Each air column is 4040 cm long at 7676 cm of Hg. When vertical, mercury moves down by xx: upper column 40+x40 + x, lower column 40−x40 - x.
  2. Boyle's law: Pup=76×4040+xP_{up} = \frac{76 \times 40}{40 + x}, Plow=76×4040−xP_{low} = \frac{76 \times 40}{40 - x}.
  3. Equilibrium of mercury: Plow=Pup+20⇒3040(140−x−140+x)=20P_{low} = P_{up} + 20 \Rightarrow 3040\left(\frac{1}{40-x} - \frac{1}{40+x}\right) = 20
  4. ⇒x2+304x−1600=0⇒x=−304+988162≈5.18\Rightarrow x^2 + 304x - 1600 = 0 \Rightarrow x = \frac{-304 + \sqrt{98816}}{2} \approx 5.18 cm
  5. So the answer is (b) 5.18 cm.
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