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JEE Main 2008 (AIEEE) · Gas Laws & Ideal Gas Equation

Gas Laws & Ideal Gas Equation question from JEE Main 2008 (AIEEE)

Q80JEE Main 2008 · AIEEEDifficult

Gas Laws & Ideal Gas Equation

An insulated container of gas has two chambers separated by an insulating partition. One of the chambers has volume V1V_1 and contains ideal gas at pressure P1P_1 and temperature T1T_1. The other chamber has volume V2V_2 and contains ideal gas at pressure P2P_2 and temperature T2T_2. If the partition is removed without doing any work on the gas, the final equilibrium temperature of the gas in the container will be

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Answer: (a)

  1. Insulated and no work, so total internal energy is conserved: n1CvT1+n2CvT2=(n1+n2)CvTn_1C_vT_1 + n_2C_vT_2 = (n_1 + n_2)C_vT.
  2. Moles: n1=P1V1RT1n_1 = \frac{P_1V_1}{RT_1}, n2=P2V2RT2n_2 = \frac{P_2V_2}{RT_2}.
  3. T=P1V1+P2V2P1V1T1+P2V2T2=T1T2(P1V1+P2V2)P1V1T2+P2V2T1T = \frac{P_1V_1 + P_2V_2}{\frac{P_1V_1}{T_1} + \frac{P_2V_2}{T_2}} = \frac{T_1T_2(P_1V_1 + P_2V_2)}{P_1V_1T_2 + P_2V_2T_1}
  4. So the answer is (a).
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