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Gas Laws & Ideal Gas Equation question from NEET 2025

Q25NEET 2025Medium

Gas Laws & Ideal Gas Equation

An oxygen cylinder of volume 30 litre has 18.20 moles of oxygen. After some oxygen is withdrawn from the cylinder, its gauge pressure drops to 11 atmospheric pressures at temperature 27∘C27^\circ\text{C}. The mass of the oxygen withdrawn from the cylinder is nearly equal to:

[Given, R=10012 J mol−1 K−1R = \frac{100}{12}\text{ J mol}^{-1}\text{ K}^{-1}, and molecular mass of O2=32, 1\text{O}_2 = 32,\ 1 atm pressure =1.01×105 N/m2= 1.01 \times 10^{5}\text{ N/m}^{2}]

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Answer: (a)

  1. Absolute pressure = gauge + 1 atm =12= 12 atm =12×1.01×105=1.212×106= 12 \times 1.01 \times 10^5 = 1.212 \times 10^6 Pa.
  2. Moles left: n=PVRT=1.212×106×0.03010012×300=363602500=14.54n = \dfrac{PV}{RT} = \dfrac{1.212 \times 10^6 \times 0.030}{\frac{100}{12} \times 300} = \dfrac{36360}{2500} = 14.54 mol
  3. Moles withdrawn =18.20−14.54=3.66= 18.20 - 14.54 = 3.66 mol
  4. Mass =3.66×32≈117= 3.66 \times 32 \approx 117 g ≈0.116\approx 0.116 kg
  5. So the answer is (a) 0.116 kg.
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