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JEE Main 2025 (4 Apr, Shift 1) · Molecular Speeds & Maxwell Distribution

Molecular Speeds & Maxwell Distribution question from JEE Main 2025 (4 Apr, Shift 1)

Q21JEE Main 2025 · 4 APR · SHIFT 1Medium

Molecular Speeds & Maxwell Distribution

Consider the sound wave travelling in ideal gases of He, CH4\text{He, CH}_4, and CO2\text{CO}_2. All the gases have the same ratio Pρ\frac{P}{\rho}, where PP is the pressure and ρ\rho is the density. The ratio of the speed of sound through the gases VHe:VCH4:VCO2V_{\text{He}} : V_{\text{CH}_4} : V_{\text{CO}_2} is given by

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Answer: (c)

  1. v=γPρv = \sqrt{\frac{\gamma P}{\rho}}; same Pρ\frac{P}{\rho}, so v∝γv \propto \sqrt\gamma
  2. He (monatomic) γ=53\gamma = \frac{5}{3}; CH4_4 (non-linear polyatomic) γ=43\gamma = \frac{4}{3}; CO2_2 (linear, taken like diatomic) γ=75\gamma = \frac{7}{5}
  3. So the answer is (c) 53:43:75\sqrt{\frac{5}{3}} : \sqrt{\frac{4}{3}} : \sqrt{\frac{7}{5}}.
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