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MHT CET 2023 (12 May, Shift 2) · Specific Heats of Gases - Cp, Cv, γ & Mayer's Relation

Specific Heats of Gases - Cp, Cv, γ & Mayer's Relation question from MHT CET 2023 (12 May, Shift 2)

Q24MHT CET 2023 · 12 MAY · SHIFT 2Easy

Specific Heats of Gases - Cp, Cv, γ & Mayer's Relation

For polyatomic gases, the ratio of molar specific heat at constant pressure to constant volume is ( f=f = degrees of freedom)

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Answer: (d)

  1. Polyatomic molecule with ff vibrational modes: Cv=(3+f)RC_v = (3+f)R (3 translational + 3 rotational halves give 3R3R, each vibrational mode gives RR).
  2. Cp=Cv+R=(4+f)RC_p = C_v + R = (4+f)R
  3. γ=4+f3+f\gamma = \frac{4+f}{3+f}
  4. So the answer is (d) 4+f3+f\frac{4+f}{3+f}.
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