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JEE Main 2022 (25 Jul, Shift 2) · Molecular Speeds & Maxwell Distribution

Molecular Speeds & Maxwell Distribution question from JEE Main 2022 (25 Jul, Shift 2)

Q59JEE Main 2022 · 25 JUL · SHIFT 2Difficult

Molecular Speeds & Maxwell Distribution

Sound travels in a mixture of two moles of helium and n moles of hydrogen. If rms speed of gas molecules in the mixture is 2\sqrt{2} times the speed of sound, then the value of n will be:

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Answer: (b)

  1. vrmsvsound=3RT/MγRT/M=3γ=2⇒γmix=32\dfrac{v_{rms}}{v_{sound}} = \sqrt{\dfrac{3RT/M}{\gamma RT/M}} = \sqrt{\dfrac{3}{\gamma}} = \sqrt{2} \Rightarrow \gamma_{mix} = \dfrac{3}{2}
  2. Mixture: CV=2⋅32R+n⋅52R2+nC_V = \dfrac{2\cdot\frac{3}{2}R + n\cdot\frac{5}{2}R}{2+n}, CP=2⋅52R+n⋅72R2+nC_P = \dfrac{2\cdot\frac{5}{2}R + n\cdot\frac{7}{2}R}{2+n}
  3. γ=5+3.5n3+2.5n=1.5⇒5+3.5n=4.5+3.75n\gamma = \dfrac{5 + 3.5n}{3 + 2.5n} = 1.5 \Rightarrow 5 + 3.5n = 4.5 + 3.75n
  4. 0.25n=0.5⇒n=20.25n = 0.5 \Rightarrow n = 2
  5. So the answer is (b) 2.
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