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JEE Main 2015 (11 Apr, Shift 1) · Specific Heats of Gases - Cp, Cv, γ & Mayer's Relation

Specific Heats of Gases - Cp, Cv, γ & Mayer's Relation question from JEE Main 2015 (11 Apr, Shift 1)

Q57JEE Main 2015 · 11 APR · SHIFT 1Difficult

Specific Heats of Gases - Cp, Cv, γ & Mayer's Relation

Using equipartition of energy, the specific heat (in J kg−1{}^{-1} K−1{}^{-1}) of aluminium at room temperature can be estimated to be (atomic weight of aluminium = 27)

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Answer: (c)

  1. Solid: each atom has 3 vibrational modes, each with energy kBTk_BT, so U=3RTU = 3RT per mole and C=3RC = 3R (Dulong–Petit).
  2. C=3×8.31≈25C = 3 \times 8.31 \approx 25 J/mol K
  3. Per kg: c=250.027≈925c = \dfrac{25}{0.027} \approx 925 J kg−1^{-1} K−1^{-1}
  4. So the answer is (c) 925.
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